Radiolysis of aqueous 2,2,2-tribromoethanol solutions
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Acetonylperoxyl Radicals, CH3C0CH20 2: A Study on the y-Radiolysis and Pulse Radiolysis of Acetone in Oxygenated Aqueous Solutions
Hydroxyl radicals from the radiolysis of N20 / 0 2 (4:l)-saturated aqueous solutions of acetone (10 3 mol dm -3) react with the solute by H-abstraction thereby forming acetonyl radicals. As shown by pulse radiolysis, the acetonyl radicals rapidly add oxygen (k = 3 x 109 dm3m ol_1s_1) thereby forming acetonylperoxyl radicals which decay by second-order kinetics (2 k = 8 x 10* dm3mol 's -1). Unde...
متن کاملAcetate Peroxyl Radicals, 02CH2C0;: A Study on the y-Radiolysis and Pulse Radiolysis of Acetate in Oxygenated Aqueous Solutions
A Study on the y-Radiolysis and Pulse Radiolysis of Acetate in Oxygenated Aqueous Solutions Man Nien Schuchmann, Henryk Zegota , and Clemens von Sonntag* Max-Planck-Institut für Strahlenchemie, Stiftstraße 34—36, D-4330 Mülheim a.d. Ruhr Dedicated to Professor Dr. Dr. h. c. mult. Günther Wilke on the occasion of his 60th birthday Z. Naturforsch. 40b, 215-221 (1985); received October 24, 1984 Ac...
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ژورنال
عنوان ژورنال: Canadian Journal of Chemistry
سال: 1970
ISSN: 0008-4042,1480-3291
DOI: 10.1139/v70-430